Abstract

Carbon fiber paper (CFP) is currently the main product of the macroporous substrate (MPS) for the gas diffusion layer (GDL) of proton exchange membrane fuel cells (PEMFCs). The optimization of certain mechanical properties, electrical conductivity, thermal conductivity, air conduction, and mass transfer capabilities together with matched interaction can improve the core competitiveness of CFP. The artical conducts a detailed theoretical analysis of these conducting processes and principles based on CFP's main functions mentioned above. Thinner CFP with a wider pore channel brings about better mass permeability but unsatisfactory mechanical property. Thicker CFP with higher porosity and rougher surface results in worse electrical and thermal conductivity. Meanwhile, the temperature, pressure, time, and other fabrication parameters of CFP are also discussed. With so many contradictories, how to make a balance for real PEMFCs operation and reduce the cost would be a practical strategy for the optimization of CFP in the future.

References

1.
Xie
,
F.
,
Shao
,
Z.
,
Hou
,
M.
,
Yu
,
H.
,
Song
,
W.
,
Sun
,
S.
,
Zhou
,
L.
, and
Yi
,
B.
,
2019
, “
Recent Progresses in H2-PEMFC at DICP
,”
J. Energy Chem
,
36
, pp.
129
140
. 10.1016/j.jechem.2019.07.012
2.
Park
,
S.
,
Lee
,
J. W.
, and
Popov
,
B. N.
,
2012
, “
A Review of Gas Diffusion Layer in PEM Fuel Cells: Materials and Designs
,”
Int. J. Hydrogen Energy
,
37
(
7
), pp.
5850
5865
. 10.1016/j.ijhydene.2011.12.148
3.
Omrani
,
R.
, and
Shabani
,
B.
,
2017
, “
Gas Diffusion Layer Modifications and Treatments for Improving the Performance of Proton Exchange Membrane Fuel Cells and Electrolysers: A Review
,”
Int. J. Hydrogen Energy
,
42
(
47
), pp.
28515
28536
. 10.1016/j.ijhydene.2017.09.132
4.
Omrani
,
R.
, and
Shabani
,
B.
,
2019
, “
Review of Gas Diffusion Layer for Proton Exchange Membrane-Based Technologies With a Focus on Unitised Regenerative Fuel Cells
,”
Int. J. Hydrogen Energy
,
44
(
7
), pp.
3834
3860
. 10.1016/j.ijhydene.2018.12.120
5.
Ozden
,
A.
,
Shahgaldi
,
S.
,
Li
,
X.
, and
Hamdullahpur
,
F.
,
2019
, “
A Review of Gas Diffusion Layers for Proton Exchange Membrane Fuel Cells—With a Focus on Characteristics, Characterization Techniques, Materials and Designs
,”
Prog. Energy Combust. Sci.
,
74
, pp.
50
102
. 10.1016/j.pecs.2019.05.002
6.
Han
,
M.
,
Xu
,
J. H.
,
Chan
,
S. H.
, and
Jiang
,
S. P.
,
2008
, “
Characterization of Gas Diffusion Layers for PEMFC
,”
Electrochim. Acta
,
53
(
16
), pp.
5361
5367
. 10.1016/j.electacta.2008.02.057
7.
Kitahara
,
T.
,
Konomi
,
T.
, and
Nakajima
,
H.
,
2010
, “
Microporous Layer Coated Gas Diffusion Layers for Enhanced Performance of Polymer Electrolyte Fuel Cells
,”
J. Power Sources
,
195
(
8
), pp.
2202
2211
. 10.1016/j.jpowsour.2009.10.089
8.
Anderson
,
R.
,
Blanco
,
M.
,
Bi
,
X.
, and
Wilkinson
,
D. P.
,
2012
, “
Anode Water Removal and Cathode Gas Diffusion Layer Flooding in a Proton Exchange Membrane Fuel Cell
,”
Int. J. Hydrogen Energy
,
37
(
21
), pp.
16093
16103
. 10.1016/j.ijhydene.2012.08.013
9.
Park
,
S.
,
Lee
,
J. W.
, and
Popov
,
B. N.
,
2006
, “
Effect of Carbon Loading in Microporous Layer on PEM Fuel Cell Performance
,”
J. Power Sources
,
163
(
1
), pp.
357
363
. 10.1016/j.jpowsour.2006.09.020
10.
Wang
,
X. L.
,
Zhang
,
H. M.
,
Zhang
,
J. L.
,
Xu
,
H. F.
,
Tian
,
Z. Q.
,
Chen
,
J.
,
Zhong
,
H. X.
,
Liang
,
Y. M.
, and
Yi
,
B. L.
,
2006
, “
Micro-Porous Layer With Composite Carbon Black for PEM Fuel Cells
,”
Electrochim. Acta
,
51
(
23
), pp.
4909
4915
. 10.1016/j.electacta.2006.01.048
11.
Gostick
,
J. T.
,
Fowler
,
M. W.
, and
Pritzker
,
M. D.
,
2006
, “
In-Plane and Through-Plane Gas Permeability of Carbon Fiber Electrode Backing Layers
,”
J. Power Sources
,
162
(
1
), pp.
228
238
. 10.1016/j.jpowsour.2006.06.096
12.
Kakhki
,
R.
,
2014
, “
A Review to Recent Developments in Modification of Carbon Fiber Electrodes
,”
Arabian J. Chem.
,
12
(
7
), pp.
1783
1794
. 10.1016/j.arabjc.2014.11.058
13.
Wu
,
Z.
,
2008
, “
Modeling and Parametric Study of Electrical Contact Resistance in PEM Fuel Cells
,”
Ph.D. dissertation
,
Tianjin University
,
Tianjin
.
14.
Cindrella
,
L.
,
Kannan
,
A. M.
,
Lin
,
J. F.
,
Saminathan
,
K.
,
Ho
,
Y.
,
Lin
,
C. W.
, and
Wertz
,
J.
,
2009
, “
Gas Diffusion Layer for Proton Exchange Membrane Fuel Cells—A Review
,”
J. Power Sources
,
194
(
1
), pp.
146
160
. 10.1016/j.jpowsour.2009.04.005
15.
Fishman
,
J.
,
2010
, “
Investigation of Surface Properties and Heterogeneity in Gas Diffusion Layers for Polymer Electrolyte Membrane Fuel Cells
,”
Master thesis
,
University of Toronto
,
Canada
.
16.
Nabovati
,
A.
,
Hinebaugh
,
J.
,
Bazylak
,
A.
, and
Amon
,
C. H.
,
2014
, “
Effect of Porosity Heterogeneity on the Permeability and Tortuosity of Gas Diffusion Layers in Polymer Electrolyte Membrane Fuel Cells
,”
J. Power Sources
,
248
, pp.
83
90
. 10.1016/j.jpowsour.2013.09.061
17.
Chahal
,
R.
,
Adnan
,
A.
,
Reifsnider
,
K.
,
Raihan
,
M. R.
,
Wu
,
Y. T.
,
Vadlamudi
,
V.
, and
Elenchezhian
,
M. R. P.
,
2018
, “
Molecular Dynamics for the Prediction of the Interfacial Shear Stress and Interface Dielectric Properties of Carbon Fiber Epoxy Composites
,”
Proceedings of the American Society for Composites—Thirty-Third Technical Conference
,
Nov. 7
. http://dx.doi.org/10.12783/asc33/25919
18.
Matula
,
R. A.
,
1979
, “
Electrical Resistivity of Copper, Gold, Palladium, and Silver
,”
J. Phys. Chem. Ref. Data
,
8
(
4
), pp.
1147
1298
. 10.1063/1.555614
19.
Eranna
,
G.
,
2014
,
Crystal Growth and Evaluation of Silicon for VLSI and ULSI
,
CRC Press
,
Boca Raton, FL
.
20.
Pauleau
,
Y.
, and
Barna
,
P. B.
,
1997
,
Protective Coatings and Thin Films: Synthesis, Characterization and Applications
,
Kluwer Academic Publishers
,
Amsterdam
.
21.
Serway
,
R. A.
,
1998
,
Principles of Physics
,
Saunders College Pub.
,
Fort Worth, TX
.
22.
Pierson
,
H. O.
,
2012
,
Handbook of Carbon, Graphite, Diamonds and Fullerenes: Processing, Properties and Applications
,
Noyes Publications
,
Norwich, UK
.
23.
Balandin
,
A. A.
,
Ghosh
,
S.
,
Bao
,
W.
,
Calizo
,
I.
,
Teweldebrhan
,
D.
,
Miao
,
F.
, and
Lau
,
C. N.
,
2008
, “
Superior Thermal Conductivity of Single-Layer Graphene
,”
Nano Lett.
,
8
(
3
), pp.
902
907
. 10.1021/nl0731872
24.
Buerschaper
,
R. A.
,
1944
, “
Thermal and Electrical Conductivity of Graphite and Carbon at Low Temperatures
,”
Int. J. Appl. Phys.
,
15
(
5
), pp.
452
454
. 10.1063/1.1707454
25.
Wang
,
C.
,
2016
, “
Study on Thermal Conductivity and Mechanical Properties of Phenolic Resin Composites
,”
Master thesis
,
Beijing University of Chemical Technology
,
Beijing
.
26.
Meng
,
H.
, and
Wang
,
C. Y.
,
2004
, “
Electron Transport in PEFCs
,”
J. Electrochem. Soc.
,
151
(
3
), p.
A358
. 10.1149/1.1641036
27.
Guo
,
F.
,
You
,
X.
,
Xu
,
X.
, and
Zhao
,
Z.
,
2013
, “
Effect of Residual Carbon on Surface Resistivity of Carbon Paper in Fuel Cell
,”
Chin. J. Power Sources
,
37
(
10
), pp.
1770
1772
.
28.
Al-Baghdadi
,
M.
, and
Sadiq
,
M. A.
,
2011
, “
Optimal Design of PEM Fuel Cells to Generate Maximum Power: A CFD Study
,”
Int. J. Energy Environ.
,
2
(
6
), pp.
953
962
.
29.
Jordan
,
L. R.
,
Shukla
,
A.
,
Behrsing
,
T.
,
Avery
,
N.
,
Muddle
,
B. C.
, and
Forsyth
,
M.
,
2000
, “
Diffusion Layer Parameters Influencing Optimal Fuel Cell Performance
,”
J. Power Sources
,
86
(
1–2
), pp.
250
254
. 10.1016/S0378-7753(99)00489-9
30.
Lee
,
H. K.
,
Park
,
J. H.
,
Kim
,
D. Y.
, and
Lee
,
T. H.
,
2004
, “
A Study on the Characteristics of the Diffusion Layer Thickness and Porosity of the PEMFC
,”
J. Power Sources
,
131
(
1–2
), pp.
200
206
. 10.1016/j.jpowsour.2003.12.039
31.
Heinzel
,
A.
,
Mahlendorf
,
F.
,
Niemzig
,
O.
, and
Kreuz
,
C.
,
2004
, “
Injection Moulded Low Cost Bipolar Plates for PEM Fuel Cells
,”
J. Power Sources
,
131
(
1–2
), pp.
35
40
. 10.1016/j.jpowsour.2004.01.014
32.
Blunk
,
R. H.
,
Lisi
,
D. J.
,
Yoo
,
Y. E.
, and
Tucker
C. L.
, III
,
2003
, “
Enhanced Conductivity of Fuel Cell Plates Through Controlled Fiber Orientation
,”
AIChE J.
,
49
(
1
), pp.
18
29
. 10.1002/aic.690490104
33.
Sammes
,
N.
,
2006
,
Fuel Cell Technology: Reaching Towards Commercialization
,
Springer Science & Business Media
,
London, UK
.
34.
Chang
,
W.
,
Hwang
,
J.
,
Weng
,
F.
, and
Chan
,
S.
,
2007
, “
Effect of Clamping Pressure on the Performance of a PEM Fuel Cell
,”
J. Power Sources
,
166
(
1
), pp.
149
154
. 10.1016/j.jpowsour.2007.01.015
35.
Gasteiger
,
H.
,
Gu
,
W.
,
Makharia
,
R.
,
Mathias
,
M.
, and
Sompalli
,
B.
,
2010
, “Beginning of Life MEA Performance—Efficiency Loss Contributions,”
Handbook of Fuel Cells
,
W.
Vielstich
,
A.
Lamm
,
H. A.
Gasteiger
, and
H.
Yokokawa
, eds.,
John Wiley & Sons
,
New York
. 10.1002/9780470974001.f303051
36.
Hentall
,
P. L.
,
Lakeman
,
J. B.
,
Mepsted
,
G. O.
,
Adcock
,
P. L.
, and
Moore
,
J. M.
,
1999
, “
New Materials for Polymer Electrolyte Membrane Fuel Cell Current Collectors
,”
J. Power Sources
,
80
(
1–2
), pp.
235
241
. 10.1016/S0378-7753(98)00264-X
37.
Berning
,
T.
, and
Djilali
,
N.
,
2003
, “
Three-Dimensional Computational Analysis of Transport Phenomena in a PEM Fuel Cell—A Parametric Study
,”
J. Power Sources
,
124
(
2
), pp.
440
452
. 10.1016/S0378-7753(03)00816-4
38.
Ehite
,
E. H.
,
2016
, “
Study of Two-Phase Flow Pressure Drop Characteristics in Proton Exchange Membrane (PEM) Fuel Cell Flow Channels of Different Geometries
,” Master thesis,
Michigan Technological University
,
Michigan
.
39.
Lister
,
S.
, and
McLean
,
G.
,
2004
, “
PEM Fuel Cell Electrodes
,”
J. Power Sources
,
130
(
1–2
), pp.
61
76
. 10.1016/j.jpowsour.2003.12.055
40.
Bernardi
,
D. M.
,
1992
, “
A Mathematical Model of the Solid-Polymer-Electrolyte Fuel Cell
,”
J. Electrochem. Soc.
,
139
(
9
), p.
2477
. 10.1149/1.2221251
41.
Burlatsky
,
S. F.
,
Atrazhev
,
V. V.
,
Gummalla
,
M.
,
Condit
,
D. A.
, and
Liu
,
F.
,
2009
, “
The Impact of Thermal Conductivity and Diffusion Rates on Water Vapor Transport Through Gas Diffusion Layers
,”
J. Power Sources
,
190
(
2
), pp.
485
492
. 10.1016/j.jpowsour.2008.12.131
42.
Owejan
,
J. P.
,
Owejan
,
J. E.
,
Gu
,
W.
,
Trabold
,
T. A.
,
Tighe
,
T. W.
, and
Mathias
,
M. F.
,
2010
, “
Water Transport Mechanisms in PEMFC Gas Diffusion Layers
,”
J. Electrochem. Soc.
,
157
(
10
), p.
B1456
. 10.1093/bja/86.1.135
43.
Nam
,
J. H.
, and
Kaviany
,
M.
,
2003
, “
Effective Diffusivity and Water-Saturation Distribution in Single- and Two-Layer PEMFC Diffusion Medium
,”
Int. J. Heat Mass Transfer
,
46
(
24
), pp.
4595
4611
. 10.1016/S0017-9310(03)00305-3
44.
Pasaogullari
,
U.
, and
Wang
,
C. Y.
,
2004
, “
Liquid Water Transport in Gas Diffusion Layer of Polymer Electrolyte Fuel Cells
,”
Electrochim. Acta
,
151
(
3
), pp.
7936
7945
. 10.1149/1.1646148
45.
Litster
,
S.
,
Sinton
,
D.
, and
Djilali
,
N.
,
2006
, “
Ex Situ Visualization of Liquid Water Transport in PEM Fuel Cell Gas Diffusion Layers
,”
J. Power Sources
,
154
(
1
), pp.
95
105
. 10.1016/j.jpowsour.2005.03.199
46.
Bazylak
,
A.
,
Sinton
,
D.
, and
Djilali
,
N.
,
2008
, “
Dynamic Water Transport and Droplet Emergence in PEMFC Gas Diffusion Layers
,”
J. Power Sources
,
176
(
1
), pp.
240
246
. 10.1016/j.jpowsour.2007.10.066
47.
Bazylak
,
A.
,
Sinton
,
D.
, and
Liu
,
Z. S.
,
2007
, “
Effect of Compression on Liquid Water Transport and Microstructure of PEMFC Gas Diffusion Layers
,”
J. Power Sources
,
163
(
2
), pp.
784
792
. 10.1016/j.jpowsour.2006.09.045
48.
Liang
,
H.
, and
Ping
,
C.
,
2010
, “
Lattice Boltzmann Simulations of Water Transport in Gas Diffusion Layer of a Polymer Electrolyte Membrane Fuel Cell
,”
J. Power Sources
,
195
(
12
), pp.
3870
3881
. 10.1016/j.jpowsour.2009.11.125
49.
Manke
,
I.
,
Hartnig
,
C.
,
Gruenerbel
,
M.
,
Lehnert
,
W.
,
Kardjilov
,
N.
,
Haibel
,
A.
,
Hilger
,
A.
,
Banhart
,
J.
, and
Riesemeier
,
H.
,
2007
, “
Investigation of Water Evolution and Transport in Fuel Cells With High Resolution Synchrotron X-Ray Radiography
,”
Appl. Phys. Lett.
,
90
(
17
), pp.
174105.1
174105.3
. 10.1063/1.2731440
50.
Wang
,
X.
,
2006
, “
Studies on Membrane Electrode Assembly of Proton Exchange Membrane Fuel Cells
,”
Ph.D. dissertation
,
Dalian institute of Chemical Physics, Chinese Academy of Sciences
,
Dalian, China
.
51.
Yue
,
L.
,
2017
, “
Effect of Hydrophobic Treatment on the Mass Transfer Characteristics of PEMFC Gas Diffusion Layer
,”
Master thesis
,
Tianjin University
,
Tianjin, China
.
52.
Zhan
,
Z.
,
Xiao
,
J.
,
Li
,
D.
,
Pan
,
M.
, and
Yuan
,
R.
,
2006
, “
Effects of Porosity Distribution Variation on the Liquid Water Flux Through Gas Diffusion Layers of PEM Fuel Cells
,”
J. Power Sources
,
160
(
2
), pp.
1041
1048
. 10.1016/j.jpowsour.2006.02.060
53.
Ning
,
Z.
,
Jinsheng
,
X.
,
Zhigang
,
Z.
, and
Mu
,
P.
,
2010
, “
Effects of Random Porosity Distribution of Gas Diffusion Layer on Fuel Cell Performance
,”
J. Wuhan Univ. Technol.
,
03
(
34
), pp.
600
603
. 10.3963/j.issn.1006-2823.2010.03.043
54.
Liu
,
K.
,
Zhang
,
Y.
,
Liu
,
Y.
,
Zhan
,
Z.
, and
Xiao
,
J.
,
2008
, “
Effect of Alternative Porosity Distribution of GDL Plane on PEM Fuel Cell Performance
,”
J. Wuhan Univ. Technol. Mater. Sci. Ed.
,
30
(
10
), pp.
127
130
.
55.
Yu
,
J.
,
Yoshikawa
,
Y.
,
Matsuura
,
T.
,
Islam
,
M. N.
, and
Hori
,
M.
,
2005
, “
Preparing Gas-Diffusion Layers of PEMFCs With a Dry Deposition Technique
,”
ECS Solid State Lett.
,
8
(
3
), p.
A152
. 10.1149/1.1854119
56.
Wang
,
S. Z.
,
Huang
,
N. K.
, and
Li
,
L. X.
,
2003
, “
Gas Diffusion Layer for Polymer Electrolyte Membrane Fuel Cell Electrodes—Preparation of Carbon Fiber Paper
,”
Acta Sci. Nat. Univ. Sunyatseni
,
42
, pp.
57
59
.
57.
Xu
,
H. F.
,
2006
, “
Studies on Fabrication of Micro-Porous Layer in PEMFC
,”
Master thesis
,
Dalian institute of Chemical Physics, Chinese Academy of Sciences
,
Dalian, China
.
You do not currently have access to this content.