Abstract
Water management is a critical design issue for polymer electrolyte membrane (PEM) fuel cells, because the PEM must be maintained at the proper water content to remain ionically conducting without flooding the electrodes. Furthermore, portable PEM power systems should operate at water balance to minimize weight. This paper presents the basic design relationships that govern water balance in a PEM fuel cell. Specific calculations are presented based on data from hydrogen/air and direct methanol fuel cells currently under development for portable power systems. We will show how the water balance operating point depends on the cell operating parameters and show the sensitivity to off-design conditions.
1.
Larminie
, J.
, and Dicks
, A.
, 2000, Fuel Cell Systems Explained
, 1st ed., Wiley
, West Sussex, England, p. 308
.2.
NETL
, 2000, Fuel Cell Handbook
, 5th ed., U.S. Department of Energy National Energy Technology Laboratory
, Morgantown, WV DOE/NETL-2000/1110.3.
DuPont
, 2000, Dupont Nafion® perfluorinated polymer products
, NAE101, available at http://www.dupont.com/teflon/fuelcells/pdf/nae101.pdf, accessed July 9, 2002.4.
Surumpudi
, S.
, et al., inventor; California Institute of Technology/JPL, assignee. Direct methanol feed fuel cell and system. USA patent 6,303,244 B1. October 16, 2001.5.
Hockaday
, R. G.
, DeJohn
, M.
, Navas
, C.
, and Turner
, P. S.
, 2000, “A better power supply for portable electronics: Microfuel cells
,” 2000 Fuel Cell Seminar, pp. 791
–794
.6.
Gottesfeld
, S.
, Ren
, X.
, Zelenay
, P.
, Dinh
, H.
, Guyon
, F.
, and Davey
, J.
2000, “Advances in direct methanol fuel cell science & technology at Los Alamos National Laboratory
,” Los Alamos National Laboratory
, Los Alamos, NM.7.
St-Pierre
, J.
, Wilkinson
, D. P.
, Knights
, S.
, and Bos
, M. L.
, 2000, “Relationships between water management, contamination, and lifetime degradation in PEFC
.” J. New Mater. Electrochem. Syst.
1480-2422 3
, pp. 99
–106
.8.
McCune
, R.
, 2001, “Special Operations Forces (SOF) mission analysis (power requirements)
,” Dept. of the Navy, Office of Special Technology (OSTO).9.
Bernardi
, D. M.
, 1990, “Water Balance Calculations for Solid-Polymer-Electrolyte Fuel Cells
,” J. Electrochem. Soc.
0013-4651 137
(11
), pp. 3344
–3350
.10.
Springer
, T. E.
, Zawodzinski
, T. A.
, and Gottesfeld
, S.
, 1991, “Polymer Electrolyte Fuel Cell Model
,” J. Electrochem. Soc.
0013-4651 138
(8
), pp. 2334
–2342
.11.
Bernardi
, D. M.
, and Verbrugge
, M. W.
, 1992, “A Mathematical Model of the Solid-Polymer-Electrolyte Fuel Cell
,” J. Electrochem. Soc.
0013-4651 139
(9
), pp. 2477
–2491
.12.
Nguyen
, T. V.
, and White
, R. E.
, 1993, “A Water and Heat Management Model for Proton-Exchange-Membrane Fuel Cells
,” J. Electrochem. Soc.
0013-4651 140
(8
), pp. 2178
–2186
.13.
Narayanan
, S. R.
, Valdez
, T.
, Rohatgi
, N.
, Christiansen
, J.
, Chun
, W.
, Voecks
, G.
, and Halpert
, G.
, 1998, “Factors Affecting the Design of Direct Methanol Fuel Cell Systems
,” Proceedings of the 38th Power Sources Conference
, pp. 461
–465
.14.
Picot
, D.
, Metkemeijer
, R.
, Bezian
, J. J.
, and Rouveyre
, L.
, 1998, “Impact of the Water Symmetry Factor on Humidifcation and Cooling Strategies for PEM Fuel Cell Stacks
,” J. Power Sources
0378-7753 75
(1998
), pp. 251
–260
.15.
Scott
, K.
, Taama
, W. M.
, and Argyropoulos
, P.
, 1999, “Engineering Aspects of the Direct Methanol Fuel Cell System
,” J. Power Sources
0378-7753 79
, pp. 43
–59
.16.
Scott
, K.
, Argyropoulos
, P.
, and Taama
, W. M.
, 2000, “Modelling Transport Phenomena and Performance of Direct Methanol Fuel Cell Stacks
,” Trans. Inst. Chem. Eng., Part A
0263-8762 78
, pp. 881
–888
.17.
St-Pierre
, J.
, Wilkinson
, D. P.
, Knights
, S.
, and Bos
, M. L.
, “Relationships Between Water Management, Contamination, and Lifetime Degradation in PEFC
,” J. New Mater. Electrochem. Syst.
1480-2422 3
, pp. 99
–106
.18.
Bonville
, L. J.
, and Yang
, D.
, 2000, “System and Method of Water Management in the Operation of a Fuel Cell
,” International Fuel Cells, South Windsor, CT, assignee, USA Patent 6,015,634, Jan 2000.19.
Ahmed
, S.
, Kopasz
, J.
, Kumar
, R.
, and Krumpelt
, M.
, 2002, “Water Balance in Polymer Electrolyte Fuel Cell System
,” J. Power Sources
0378-7753 112
, pp. 519
–530
.20.
Tuber
, K.
, Pocza
, D.
, and Hebling
, C.
, 2003, “Visualization of Water Buildup in the Cathode of a Transparent PEM Fuel Cell
,” J. Power Sources
0378-7753 12
, pp. 403
–414
.21.
Narayanan, loc cit.
Copyright © 2004
by American Society of Mechanical Engineers
You do not currently have access to this content.