In this paper, we give a complete description of the process of determining two-phase material parameters for a gas diffusion layer: Starting from a 3D tomography image of the gas diffusion layer the distribution of gas and water phases is determined using the pore morphology method. Using these 3D phase distributions, we are able to determine permeability, diffusivity, and heat conductivity as a function of the saturation of the porous medium with comparatively low numerical costs. Using a reduced model for the compression of the gas diffusion layer, the influence of the compression on the parameter values is studied.
Issue Section:
Research Papers
1.
Mathias
, M.
, Roth
, J.
, Fleming
, J.
, and Lehnert
, W.
, 2003, “Diffusion Media Materials and Characterisation
,” Handbook of Fuel Cells—Fundamentals, Technology and Applications
, Vol. 3
, W.
Vielstich
, H.
Gasteiger
, and A.
Lamm
, eds., Wiley
, New York
.2.
Baschuk
, J. J.
, and Li
, X.
, 2004 “A General Formulation for a Mathematical PEM Fuel Cell Model
,” J. Power Sources
0378-7753, 142
, pp. 134
–153
.3.
Kühn
, K.
, Ohlberger
, M.
, Schumacher
, J. O.
, Ziegler
, C.
, and Klöfkorn
, R.
, 2003, “A Dynamic Two-Phase Flow Model of Proton Exchange Membrane Fuel Cells
,” Proceedings of the Second European PEFC Forum
, Vol. 1
, pp. 283
–296
.4.
Pharoah
, J. G.
, 2005, “On the Permeability of Gas Diffusion Media Used in PEM Fuel Cells
,” J. Power Sources
0378-7753, 144
, pp. 77
–82
.5.
Ngo
, N. D.
, and Tamma
, K. K.
, 2004, “Complex Three-Dimensional Microstructural Permeability Prediction of Porous Fibrous Media With and Without Compaction
,” Int. J. Numer. Methods Eng.
0029-5981, 60
, pp. 1741
–1757
.6.
Acosta
, M.
, Merten
, C.
, Eigenberger
, G.
, Class
, H.
, Helmig
, R.
, Thoben
, B.
, and Müller-Steinhagen
, H.
, 2006, “Modeling Non-Isothermal Two-Phase Multicomponent Flow in the Cathode of PEM Fuel Cells
,” J. Power Sources
0378-7753, 159
, pp. 1123
–1141
.7.
Torquato
, S.
, 2002, Random Heterogeneous Materials
, Springer
, New York
.8.
Schulz
, V. P.
, Mukherjee
, P. P.
, Becker
, J.
, Wiegmann
, A.
, and Wang
, C. Y.
, 2007, “Modelling of Two-Phase Behaviour in the Gas Diffusion Medium of PEFCs Via Full Morphology Approach
,” J. Electrochem. Soc.
0013-4651, 154
(4
), pp. 419
–426
.9.
Cloetens
, P.
, Ludwig
, W.
, Boller
, E.
, Helfen
, L.
, Salvo
, L.
, Mache
, R.
, and Schlenker
, M.
, 2002, “Quantitative Phase Contrast Tomography Using Coherent Synchrotron Radiation
,” Proc. SPIE
0277-786X, 4503
, pp. 82
–91
.10.
Helfen
, L.
, Baumbach
, T.
, Schladitz
, K.
, and Ohser
, J.
, 2003, “Determination of Structural Properties of Light Materials by Three-Dimensional Synchrotron-Radiation Imaging and Image Analysis
,” Imaging & Microscopy
, 5
, pp. 55
–57
.11.
Hilpert
, M.
, and Miller
, C.
, 2001, “Pore-Morphology-Based Simulation of Drainage in Totally Wetting Porous Media
,” Adv. Water Resour.
0309-1708, 24
, pp. 243
–255
.12.
Litster
, S.
, Sinton
, S.
, and Djilali
, N.
, 2005, “Ex Situ Visualization of Liquid Water Transport in PEM Fuel Cell Gas Diffusion Layers
,” J. Power Sources
0378-7753, 154
, pp. 95
–105
.13.
Jena
, A.
, and Gupta
, K.
, 2002, “Characterisation of Pore Structure of Filtration Media
,” Fluid/Part. Sep. J.
1043-2558, 4
(3
), pp. 227
–241
.14.
Hornung
, U.
, 1997, Homogenization and Porous Media
, Springer
, New York
.15.
Wiegmann
, A.
, and Zemitis
, A.
, 2006, “EJ-HEAT: A Fast Explicit Jump Harmonic Averaging Solver for the Effective Heat Conductivity of Composite Materials
,” Fraunhofer ITWM Kaiserslautern, Technical Report 94.16.
Wiegmann
, A.
, and Zemitis
, A.
, 2007, “EJ-DIFFUSION: A Fast Explicit Jump Harmonic Averaging Solver for the Effective Diffusivity of Porous Materials
,” unpublished.17.
Wiegmann
, A.
, 2007, “Computation of the Permeability of Porous Materials From Their Microstructure by FFF-Stokes
,” Fraunhofer ITWM Kaiserslautern, Technical Report 129.18.
Wiegmann
, A.
, 2001–2007, “GeoDict Virtual Micro Structure Simulator and Material Property Predictor
,” http://www.geodict.comhttp://www.geodict.comCopyright © 2008
by American Society of Mechanical Engineers
You do not currently have access to this content.