In this study, the fluid flow and cell performance in cathode side of a proton exchange membrane (PEM) fuel cell were numerically analyzed. The problem domain consists of cathode gas channel, cathode gas diffusion layer, and cathode catalyst layer. The equations governing the motion of air, concentration of oxygen, and electrochemical reactions were numerically solved. A computer program was developed based on control volume method and SIMPLE algorithm. The mathematical model and program developed were tested by comparing the results of numerical simulations with the results from literature. Simulations were performed for different values of inlet Reynolds number and inlet oxygen mole fraction at different operation temperatures. Using the results of these simulations, the effects of these parameters on the flow, oxygen concentration distribution, current density and power density were analyzed. The simulations showed that the oxygen concentration in the catalyst layer increases with increasing Reynolds number and hence the current density and power density of the PEM fuel cell also increases. Analysis of the data obtained from simulations also shows that current density and power density of the PEM fuel cell increases with increasing operation temperature. It is also observed that increasing the inlet oxygen mole fraction increases the current density and power density.

1.
Springer
,
T.
,
Zawodzinski
,
T.
, and
Gottesfeld
,
S.
, 1991, “
Polymer Electrolyte Fuel Cell Model
,”
J. Electrochem. Soc.
0013-4651,
138
, pp.
2334
2342
.
2.
Um
,
S.
,
Wang
,
C. Y.
, and
Chen
,
K. S.
, 2000, “
Computational Fluid Dynamics Modeling of Proton Exchange Membrane Fuel Cell
,”
J. Electrochem. Soc.
0013-4651,
147
, pp.
4485
4493
.
3.
Gurau
,
V.
,
Liu
,
H.
, and
Kakaç
,
S.
, 1998, “
Two-Dimensional Model for Proton Exchange Membrane Fuel Cells
,”
AIChE J.
0001-1541,
44
, pp.
2410
2422
.
4.
Kazim
,
A.
,
Forges
,
P.
, and
Liu
,
H. T.
, 2003, “
Effects of Cathode Operating Conditions on Performance of a PEM Fuel Cell With Interdigitated Flow Fields
,”
Int. J. Energy Res.
0363-907X,
27
, pp.
401
414
.
5.
Nguyen
,
P. T.
,
Berning
,
T.
, and
Djilali
,
N.
, 2004, “
Computational Model of a PEM Fuel Cell With Serpentine Gas Flow Channels
,”
J. Power Sources
0378-7753,
130
, pp.
149
157
.
6.
Dutta
,
S.
,
Shimpalee
,
S.
, and
Van Zee
,
J. W.
, 2000, “
Three-Dimensional Numerical Simulation of Straight Channel PEM Fuel Cells
,”
J. Appl. Electrochem.
0021-891X,
30
, pp.
135
146
.
7.
Berning
,
T.
,
Lu
,
D. M.
, and
Djilali
,
N.
, 2002, “
Three-Dimensional Computational Analysis of Transport Phenomena in a PEM Fuel Cell
,”
J. Power Sources
0378-7753,
106
, pp.
284
294
.
8.
Siegel
,
C.
, and
Scheuren
,
J. J.
, 2006, “
Vergleich und Bewertung Unterschiedlicher Polymer-Elektrolyt-Membran Brennstoffzellen Modellierungsansatze
,”
Revue Technique Luxembourgeoise
,
98
, pp.
117
134
.
9.
Cheddie
,
D.
, and
Munroe
,
N.
, 2005, “
Review and Comparison of Approaches to Proton Exchange Membrane Fuel Cell Modeling
,”
J. Power Sources
0378-7753,
147
, pp.
72
84
.
10.
Haraldsson
,
K.
, and
Wipke
,
K.
, 2004, “
Evaluating PEM Fuel Cell System Models
,”
J. Power Sources
0378-7753,
126
, pp.
88
97
.
11.
Djilali
,
N.
, 2007, “
Computational Modeling of Polymer Electrolyte Membrane (PEM) Fuel Cells: Challenges and Opportunities
,”
Energy
0360-5442,
32
, pp.
269
280
.
12.
Weber
,
A. Z.
, and
Newman
,
J.
, 2004, “
Modeling Transport in Polymer-Electrolyte Fuel Cells
,”
Chem. Rev. (Washington, D.C.)
0009-2665,
104
, pp.
4679
4726
.
13.
Wang
,
C. Y.
, 2004, “
Fundamental Models for Fuel Cell Engineering
,”
Chem. Rev. (Washington, D.C.)
0009-2665,
104
, pp.
4727
4766
.
14.
Yao
,
K. Z.
,
Karan
,
K.
,
McAuley
,
K. B.
,
Oosthuizen
,
P.
,
Peppley
,
B.
, and
Xie
,
T.
, 2004, “
A Review of Mathematical Models for Hydrogen and Direct Methanol Polymer Electrolyte Membrane Fuel Cells
,”
Fuel Cells
0532-7822,
4
, pp.
3
29
.
15.
Faghri
,
A.
, and
Guo
,
Z.
, 2005, “
Challenges and Opportunities of Thermal Management Issues Related to Fuel Cell Technology and Modeling
,”
Int. J. Heat Mass Transfer
0017-9310,
48
, pp.
3891
3920
.
16.
Costamagna
,
P.
, and
Srinivasan
,
S.
, 2001, “
Quantum Jumps in the PEMFC Science and Technology From the 1960s to the Year 2000: Part I. Fundamental Scientific Aspects
,”
J. Power Sources
0378-7753,
102
, pp.
242
252
.
17.
Costamagna
,
P.
, and
Srinivasan
,
S.
, 2001, “
Quantum Jumps in the PEMFC Science and Technology From the 1960s to the Year 2000: Part II. Engineering, Technology Development and Application Aspects
,”
J. Power Sources
0378-7753,
102
, pp.
253
269
.
18.
Siegel
,
C.
, 2008, “
Review of Computational Heat and Mass Transfer Modeling in Polymer-Electrolyte-Membrane (PEM) Fuel Cells
,”
Energy
0360-5442,
33
(
9
), pp.
1331
1352
.
19.
Gülan
,
U.
, 2008, “
Numerical investigation of Fluid Flow and Heat Transfer in Gas Flow Channels of Fuel Cells
,” MS thesis, Gazi University Institute of Science and Technology.
20.
Parthasarathy
,
A.
,
Srinivasan
,
S.
, and
Appleby
,
A. J.
, 1992, “
Temperature Dependence of the Electrode Kinetics of Oxygen Reduction at the Platinium/Nafion Interface a Microelectrode Investigation
,”
J. Electrochem. Soc.
0013-4651,
139
(
9
), pp.
2530
2537
.
21.
Um
,
S.
, and
Wang
,
C. Y.
, 2003, “
Three-Dimensional Analysis of Transport and Electrochemical Reaction in Polymer Electrolyte Fuel Cells
,”
J. Power Sources
0378-7753,
125
(
1
), pp.
40
51
.
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