In this paper, a series of bio-based epoxy resins containing organic silicone were prepared from eugenol through a mild synthetic route. Then, 4,4′-diaminophenyl methane (DDM) was applied to cure these epoxy resins, and bisphenol A epoxy resin (DGEBA) was used as a control. The chemical structures of the synthesized resins were characterized by nuclear magnetic resonance (1H-NMR). Properties of the cured epoxy resins were investigated by dielectric test, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), dynamic mechanical analysis (DMA), and scanning electron microscopy (SEM). Compared with DGEBA, the bio-based epoxy resin containing cyclic organic silicon structure exhibited a dramatically lower dielectric constant at both low and high frequencies (3.46, 1 kHz, room temperature). Moreover, the silicone-modified bio-based epoxy resins demonstrated no weight loss below 325 °C and higher residues at 800 °C than that of DGEBA.
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September 2017
Research-Article
Bio-Based Epoxy Resins Derived From Eugenol With Low Dielectric Constant
Yuan Liu,
Yuan Liu
Polymer and Composites Division,
Ningbo Institute of Materials Technology and Engineering,
Chinese Academy of Sciences,
Ningbo 315201, China;
Engineering Research Center for Materials Protection of
Wear and Corrosion of Guizhou Province,
Guiyang University,
Guiyang 550005, China;
University of Chinese Academy of Sciences,
Beijing 100049, China
Ningbo Institute of Materials Technology and Engineering,
Chinese Academy of Sciences,
Ningbo 315201, China;
Engineering Research Center for Materials Protection of
Wear and Corrosion of Guizhou Province,
Guiyang University,
Guiyang 550005, China;
University of Chinese Academy of Sciences,
Beijing 100049, China
Search for other works by this author on:
Jinyue Dai,
Jinyue Dai
Polymer and Composites Division,
Ningbo Institute of Materials Technology and Engineering,
Chinese Academy of Sciences,
Ningbo 315201, China;
University of Chinese Academy of Sciences,
Beijing 100049, China
Ningbo Institute of Materials Technology and Engineering,
Chinese Academy of Sciences,
Ningbo 315201, China;
University of Chinese Academy of Sciences,
Beijing 100049, China
Search for other works by this author on:
Xiaoqing Liu,
Xiaoqing Liu
Polymer and Composites Division,
Ningbo Institute of Materials Technology and Engineering,
Chinese Academy of Sciences,
Ningbo 315201, China;
University of Chinese Academy of Sciences,
Beijing 100049, China
e-mail: liuxq@nimte.ac.cn
Ningbo Institute of Materials Technology and Engineering,
Chinese Academy of Sciences,
Ningbo 315201, China;
University of Chinese Academy of Sciences,
Beijing 100049, China
e-mail: liuxq@nimte.ac.cn
Search for other works by this author on:
Jun Luo,
Jun Luo
Engineering Research Center for Materials Protection of
Wear and Corrosion of Guizhou Province,
Guiyang University,
Guiyang 550005, China
Wear and Corrosion of Guizhou Province,
Guiyang University,
Guiyang 550005, China
Search for other works by this author on:
Shusen You,
Shusen You
Polymer and Composites Division,
Ningbo Institute of Materials Technology
and Engineering,
Chinese Academy of Sciences,
Ningbo 315201, China;
University of Chinese Academy of Sciences,
Beijing 100049, China
Ningbo Institute of Materials Technology
and Engineering,
Chinese Academy of Sciences,
Ningbo 315201, China;
University of Chinese Academy of Sciences,
Beijing 100049, China
Search for other works by this author on:
Jin Zhu,
Jin Zhu
Polymer and Composites Division,
Ningbo Institute of Materials Technology
and Engineering,
Chinese Academy of Sciences,
Ningbo 315201, China;
University of Chinese Academy of Sciences,
Beijing 100049, China
Ningbo Institute of Materials Technology
and Engineering,
Chinese Academy of Sciences,
Ningbo 315201, China;
University of Chinese Academy of Sciences,
Beijing 100049, China
Search for other works by this author on:
Songqi Ma,
Songqi Ma
Polymer and Composites Division,
Ningbo Institute of Materials Technology
and Engineering,
Chinese Academy of Sciences,
Ningbo 315201, China;
University of Chinese Academy of Sciences,
Beijing 100049, China
Ningbo Institute of Materials Technology
and Engineering,
Chinese Academy of Sciences,
Ningbo 315201, China;
University of Chinese Academy of Sciences,
Beijing 100049, China
Search for other works by this author on:
Zhen Jia
Zhen Jia
Ningbo Institute of Materials Technology
and Engineering,
Chinese Academy of Sciences,
Ningbo 315201, China;
University of Chinese Academy of Sciences,
Beijing 100049, China
and Engineering,
Chinese Academy of Sciences,
Ningbo 315201, China;
University of Chinese Academy of Sciences,
Beijing 100049, China
Search for other works by this author on:
Yuan Liu
Polymer and Composites Division,
Ningbo Institute of Materials Technology and Engineering,
Chinese Academy of Sciences,
Ningbo 315201, China;
Engineering Research Center for Materials Protection of
Wear and Corrosion of Guizhou Province,
Guiyang University,
Guiyang 550005, China;
University of Chinese Academy of Sciences,
Beijing 100049, China
Ningbo Institute of Materials Technology and Engineering,
Chinese Academy of Sciences,
Ningbo 315201, China;
Engineering Research Center for Materials Protection of
Wear and Corrosion of Guizhou Province,
Guiyang University,
Guiyang 550005, China;
University of Chinese Academy of Sciences,
Beijing 100049, China
Jinyue Dai
Polymer and Composites Division,
Ningbo Institute of Materials Technology and Engineering,
Chinese Academy of Sciences,
Ningbo 315201, China;
University of Chinese Academy of Sciences,
Beijing 100049, China
Ningbo Institute of Materials Technology and Engineering,
Chinese Academy of Sciences,
Ningbo 315201, China;
University of Chinese Academy of Sciences,
Beijing 100049, China
Xiaoqing Liu
Polymer and Composites Division,
Ningbo Institute of Materials Technology and Engineering,
Chinese Academy of Sciences,
Ningbo 315201, China;
University of Chinese Academy of Sciences,
Beijing 100049, China
e-mail: liuxq@nimte.ac.cn
Ningbo Institute of Materials Technology and Engineering,
Chinese Academy of Sciences,
Ningbo 315201, China;
University of Chinese Academy of Sciences,
Beijing 100049, China
e-mail: liuxq@nimte.ac.cn
Jun Luo
Engineering Research Center for Materials Protection of
Wear and Corrosion of Guizhou Province,
Guiyang University,
Guiyang 550005, China
Wear and Corrosion of Guizhou Province,
Guiyang University,
Guiyang 550005, China
Shusen You
Polymer and Composites Division,
Ningbo Institute of Materials Technology
and Engineering,
Chinese Academy of Sciences,
Ningbo 315201, China;
University of Chinese Academy of Sciences,
Beijing 100049, China
Ningbo Institute of Materials Technology
and Engineering,
Chinese Academy of Sciences,
Ningbo 315201, China;
University of Chinese Academy of Sciences,
Beijing 100049, China
Jin Zhu
Polymer and Composites Division,
Ningbo Institute of Materials Technology
and Engineering,
Chinese Academy of Sciences,
Ningbo 315201, China;
University of Chinese Academy of Sciences,
Beijing 100049, China
Ningbo Institute of Materials Technology
and Engineering,
Chinese Academy of Sciences,
Ningbo 315201, China;
University of Chinese Academy of Sciences,
Beijing 100049, China
Songqi Ma
Polymer and Composites Division,
Ningbo Institute of Materials Technology
and Engineering,
Chinese Academy of Sciences,
Ningbo 315201, China;
University of Chinese Academy of Sciences,
Beijing 100049, China
Ningbo Institute of Materials Technology
and Engineering,
Chinese Academy of Sciences,
Ningbo 315201, China;
University of Chinese Academy of Sciences,
Beijing 100049, China
Zhen Jia
Ningbo Institute of Materials Technology
and Engineering,
Chinese Academy of Sciences,
Ningbo 315201, China;
University of Chinese Academy of Sciences,
Beijing 100049, China
and Engineering,
Chinese Academy of Sciences,
Ningbo 315201, China;
University of Chinese Academy of Sciences,
Beijing 100049, China
1Both authors contributed equally to this paper.
2Corresponding author.
Contributed by the Electronic and Photonic Packaging Division of ASME for publication in the JOURNAL OF ELECTRONIC PACKAGING. Manuscript received February 11, 2017; final manuscript received April 19, 2017; published online June 30, 2017. Assoc. Editor: Yi-Shao Lai.
J. Electron. Packag. Sep 2017, 139(3): 031006 (7 pages)
Published Online: June 30, 2017
Article history
Received:
February 11, 2017
Revised:
April 19, 2017
Citation
Liu, Y., Dai, J., Liu, X., Luo, J., You, S., Zhu, J., Ma, S., and Jia, Z. (June 30, 2017). "Bio-Based Epoxy Resins Derived From Eugenol With Low Dielectric Constant." ASME. J. Electron. Packag. September 2017; 139(3): 031006. https://doi.org/10.1115/1.4036818
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