The effect of fluid flow on corrosion of steel in oil and gas environments involves a complex interaction of physical and chemical parameters. The basic requirement for any corrosion to occur is the existence of liquid water contacting the pipe wall, which is primarily controlled by the flow regime. The effect of flow on corrosion, or flow-accelerated corrosion, is defined by the mass transfer and wall shear stress parameters existing in the water phase that contacts the pipe wall. While existing fluid flow equations for mass transfer and wall shear stress relate to equilibrium conditions, disturbed flow introduces nonequilibrium, steady-state conditions not addressed by these equations, and corrosion testing in equilibrium conditions cannot be effectively related to corrosion in disturbed flow. The problem in relating flow effects to corrosion is that steel corrosion failures in oil and gas environments are normally associated with disturbed flow conditions as a result of weld beads, pre-existing pits, bends, flanges, valves, tubing connections, etc. Steady-state mass transfer and wall shear stress relationships to steel corrosion and corrosion testing are required for their application to corrosion of steel under disturbed flow conditions. A procedure is described to relate the results of a corrosion test directly to corrosion in an operation system where disturbed flow conditions are expected, or must be considered.

1.
Lee
A. H.
,
Sun
J. Y.
, and
Jepson
W. P.
, “
Study of Flow Regime Transitions of Oil-Water-Gas Mixtures in Horizontal Pipelines
,”
3rd International Conference ISOPE
, Vol.
II
,
1993
, pp.
159
164
.
2.
Maholtra, A., “A Study of Oil/Water Flow Characteristics in Horizontal Pipes,” MS thesis, Ohio University, Athens, OH, Oct. 1996.
3.
Zhou, X., and Jepson, W. P., Corrosion in Three-Phase Oil/Water/Gas Slug Flow in Horizontal Pipes,” CORROSION/94, NACE International, New Orleans, LA, Mar. 1994, Paper No. 94026.
4.
Kang, C., Wilkins, R., and Jepson, W. P., “The Effect of Slug Frequency on Corrosion in High Pressure Inclined Pipelines,” CORROSION/96, NACE International, Denver, CO, Mar. 1996, Paper No. 96020.
5.
Efird, K. D., et al., “Wall Shear Stress and Flow Accelerated Corrosion of Carbon Steel in Sweet Production,” Proceedings: 12th International Corrosion Congress, Houston, TX, September 19-24, 1993.
6.
Davies, J. T., “Eddy Transfer Near Solid Surfaces,” Turbulence Phenomena, Academic Press, New York, NY, 1972, pp. 121–143.
7.
Chen, Y., Moccari, A. A., and Macdonald, D. D., “The Development of Controlled Hydrodynamic Techniques for Corrosion Testing,” CORROSION/91, NACE International, Cincinnati, OH, March 11-15, 1991, Paper No. 292.
8.
Heitz, “Chemo-mechanical Effects of Flow on Corrosion,” MTI Publication No. 23, MTI Project No. 15, Materials Technology Institute, Columbus, OH, 1986.
9.
Ellison
T.
, and
Wen
C. J.
, “
Hydrodynamic Effects on Corrosion
,”
Tutorial Lectures in Electrochemical Engineering and Technology
, Richard Alkire and Theodore Beck Editors, AIChE Symposium Series, Vol.
77
, AIChE, New York, NY,
1981
, pp.
161
169
.
10.
Efird
K. D.
, “
The Effect of Fluid Dynamics on the Corrosion of Copper Base Alloys in Seawater
,”
Corrosion
, Vol.
33
, No.
1
, Jan.
1977
, pp.
3
8
.
11.
Efird
K. D.
,
Wright
E. J.
,
Boros
J. A.
, and
Hailey
T. G.
, “
Experimental Correlation of Steel Corrosion in Pipe Flow with Jet Impingement and Rotating Cylinder Laboratory Tests
,”
Corrosion
, Vol.
49
, No.
12
, Dec.
1993
, pp.
992
1003
.
12.
Townsend, A. A., The Structure of Turbulent Flow, Cambridge University Press, Cambridge, MA, 1956, pp. 194–196.
13.
Reiss
P.
, and
Hanratty
T. J.
, “
Measurement of Instantaneous Rates of Mass Transfer to a Small Sink on a Wall
,”
A.I.Ch.E. Journal
, Vol.
8
, No.
2
, May.
1962
, pp.
245
247
.
14.
Reiss
P.
, and
Hanratty
T. J.
, “
An Experimental Study of the Unsteady Nature of the Viscous Sublayer
,”
A.I.Ch.E. Journal
, Vol.
12
, No.
3
, Mar.
1963
, pp.
154
160
.
15.
Mitchell
E.
, and
Hanratty
T. J.
, “
A Study of Turbulence at a Wall Using an Electrochemical Wall Shear Stress Meter
,”
Journal of Fluid Mechanics
, Vol.
26
, Part 1,
1966
, pp.
199
221
.
This content is only available via PDF.
You do not currently have access to this content.