In the present study, a simple perfectly premixed research burner was utilized at temperatures, pressures and residence times representative of an industrial gas turbine cycle to identify the lower limit of NOx and CO emissions, and to establish an emissions benchmark for practical gas turbine combustors. In addition to experimental data, a chemical reactor model has been utilized for the prediction of the NOx and CO, based on detailed chemical reaction mechanisms. Several current kinetics mechanisms were evaluated and subsequently compared to the experimental data. In addition, sensitivity analysis was performed to identify important reactions at the conditions tested, and will be discussed.
Issue Section:
Gas Turbines: Combustion, Fuels, and Emissions
References
1.
Leonard
, G.
, and Correa
, S.
, 1990, “NOx Formation in Premixed High-Pressure Lean Methane Flames
,” Fossil Fuel Combustion Symposium: 13th Annual Energy-Sources Technology Conference and Exhibition
, New Orleans, LA
, pp. 69
–74
.2.
Johnson
, M. R.
, Littlejohn
, D.
, Nazeer
, W. A.
, Smith
, K. O.
, and Cheng
, R. K.
, 2005, “A Comparison of the Flowfields and Emissions of High-Swirl Injectors and Low-Swirl Injectors for Lean Premixed Gas Turbines
,” Proc. Combust. Inst.
, 30
, pp. 2867
–2874
.3.
Littlejohn
, D.
, and Cheng
, R. K.
, 2007, “Fuel Effects on a Low-Swirl Injector for Lean Premixed Gas Turbines
,” Proc. Combust. Inst.
, 31
(2
), pp. 3155
–3162
.4.
Cheng
, R. K.
, Littlejohn
, D.
, Nazeer
, W. A.
, and Smith
, K. O.
, 2008, “L;aboratory Studies of the Flow Field Characteristics of Low-Swirl Injectors for Application to Fuel-Flexible Turbines
,” ASME J. Eng. Gas Turbines Power
130
, p. 021501
.5.
Littlejohn
, D.
, Cheng
, R. K.
, Noble
, D. R.
, and Lieuwen
, T.
, 2010, “Laboratory Investigations of Low-Swirl Injectors Operating With Syngases
,” J. Eng. Gas Turbines Power
, 132
, p. 011502
.6.
Glarborg
, P.
, Miller
, J. A.
, and Kee
, R. J.
, 1986, “Kinetic Modeling and Sensitivity Analysis of Nitrogen Oxide Formation in Well-Stirred Reactors
,” Combust. Flame
, 65
, pp. 177
–202
.7.
Smith
, G. P.
, Golden
, D. M.
, Frenklach
, M.
, Moriarty
, N. W.
, Eiteneer
, B.
, Goldenberg
, M.
, Bowman
, C. T.
, Hanson
, R. K.
, Song
, S.
, Gardiner
, W. C.
Jr., Lissianski
, V. V.
, and Qin
, Z.
, http://www.me.berkeley.edu/gri_mech/8.
Dooley
, S.
, Burke
, M. P.
, Chaos
, M.
, Stein
, Y.
, Dryer
, F. L.
, Zhukov
, V. P.
, Finch
, O.
, Simmie
, J. M.
, and Curran
, H. J.
, 2010, “Methyl Formate Oxidation: Speciation Data, Laminar Burning Velocities, Ignition Delay Times, and a Validated Chemical Kinetic Model
,” Int. J. Chem Kin.
, 42
, pp 527
–549
.9.
Healy
, D.
, Kalitan
, D. M.
, Aul
, C. J.
, Petersen
, E. L.
, Bourque
, G.
, and Curran
, H. J.
, 2010, “Oxidation of C1-C5 Alkane Quinternary Natural Gas Mixtures at High Pressures Energy and Fuels
,” Energy Fuels
, 24
, pp. 1521
–1528
.10.
Wang
, H.
, You.
, X.
, Joshi
, A. V.
, Davis
, S. G.
, Laskin
, A.
, Egolfopoulos
, F.
, and Law
, C. K.
, 2007, “USC Mech Version II. High-Temperature Combustion Reaction Model of H2/CO/C1-C4 Compounds
,” http://ignis.usc.edu/USC_Mech_II.htm11.
Ranzi
, E.
, Dente
, M.
, Goldaniga
, A.
, Bozzano
, G.
, and Faravelli
, T.
, 2001, “Lumping Procedures in Detailed Kinetic Modelling of Gasification, Pyrolysis, Partial Oxidation and Combustion of Hydrocarbon Mixtures
,” Prog. Energy Combust. Sci.
, 27
, pp. 99
–139
.12.
Umanskii
, S.
, Bryukov
, M.
, Strelkova
, M.
, and Chernysheva
, I.
, 2009, “Kintech Mechanism
,” private communication.13.
Lefebvre
, A. H.
, 1999, Gas Turbine Combustion
,, Taylor & Francis Group
, New York
, pp. 328
–330
.Copyright © 2012
by American Society of Mechanical Engineers
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